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How to find chapters in an iTunes movie on Apple TV
To find chapters in an iTunes movie that you are watching on Apple TV, press and hold down the center button on the little aluminum remote.
In addition to the chapters, you will find other stuff, like subtitles, etc.
This is one of the disadvantages to having such a simple remote. Personally, I like the simple remote. I have been looking at the remote of my TV, by comparison, and even though I've owned it for many years, I still can't seem to find the buttons, of which there appear to be thousands.